May 22, 2012


Chlorofluorocarbons: Silent Destroyers of the Ozone Layer

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Lines of cars during rush hourWhat does your old air conditioner, freezer, refrigerator and older car all have in common? They all contain a chemical compound called chlorofluorocarbons or CFC’s, a substance that adversely reacts with the ozone layer in the atmosphere. This substance is so harmful that special equipment and strict regulations were designed to protect the population of the entire planet.


Ozone Protection


As you may know, the ozone layer in the stratosphere creates a protective shield from the harmful ultraviolet rays of the sun, particularly ultraviolet-B rays. Without this protection, a massive amount of UVB light can penetrate the atmosphere. Most experts agree that high exposure to UVB light can cause skin cancer, cataracts, and adverse changes to the immune system.


To protect the population from negative health effects the preservation of stratospheric ozone is paramount. Studying the ozone started in 1956 with measurements from the ground. In the 1970s, satellite measurements increased our understanding of the ozone. These scientific studies showed that portions of the ozone layer, particularly in the Antarctic region, are gradually thinning out with every passing year.


CFCs Effect on the Ozone Layer


In 1974, studies began to show the effects of chemicals on the ozone layer. It was discovered that a particularly hazardous chemical, chlorofluorocarbons (CFCs), was creating damage to the ozone at an extremely fast rate. CFCs were commonly used as aerosol propellants in sprays and refrigerants in appliances like refrigerators and air conditioners. However, when chemicals, like CFCs, were released into the air, they would often reach the stratosphere and catalytically breakdown the ozone. These chemicals started eating away at the ozone, like wearing out an old sweater until holes formed. Due to these research findings, in 1978, the use of CFCs as aerosol propellants, such as in hairsprays and deodorants, was banned in the US.


As scientists continued to study the ozone layer and the negative effects of chemicals on it, ozone holes were discovered. Above Antarctica and the South Pole as well as above the northern United States up to the North large holes have been appearing.


What Has Been Done to Limit CFCs


The diminished ozone protection creating greater UVB exposure allowed for a greater possibility of increased health incidents. This issue was not just a national problem, but a global one. 93 nations agreed to start a phase-out process to stop producing and using ozone-destroying substances. The international community set a unified objective of reducing CFCs by at least 50% by the year 1999.


The Clean Air Act of 1990 laid out a schedule to end the US production of these harmful chemicals. Additional CFCs uses, such as in solvents, foaming agents in plastics, and any remaining aerosol sprays, were given a production end date of 1996.


The largest source of ozone-depleting chemicals goes to CFC from air conditioners in cars. Special equipment has been designed for auto service shops to recycle the CFCs and prevent them from being released in the air. This service has been regulated since the end of 1993. Refrigerator servicing and disposal also followed similar guidelines regarding the CFCs used in refrigerants. The EPA also established a CFC certification program to test the refrigerant recovery and recycling equipment used by manufacturers and importers.


What Lies Ahead


As chemicals, such as CFCs, are banned, chemical reformulation is needed to create substitutes to continue the production of the products. So we don’t merely replace one harmful chemical with another, the EPA continues to conduct tests on replacements to ensure their safety on heath and the environment.


(2010) Repairing the Ozone Layer. Retrieved August 25, 2010. http://infousa.state.gov/government/branches/pegcaa06.html

(2010) Environmental Effects Of Chlorofluorocarbons: Will Restrictions Be Needed? Retrieved August 25, 2010. http://www.ornl.gov/sci/engineering_science_technology/eere_research_reports/electrically_driven_heat_pumps/fluids_development/cfc_and_hcfc_replacements/ornl_tm_9817/ornl_tm_9817.pdf

(2010) The Ozone Hole. Retrieved August 25, 2010. http://www.theozonehole.com/ozoneholehistory.htm

(2010) Chlorofluorocarbons and Ozone Depletion. Retrieved August 25, 2010. http://www.ciesin.columbia.edu/TG/OZ/cfcozn.html

(2010) Production and Use of Chlorofluorocarbons. Retrieved August 25, 2010. http://www.ciesin.columbia.edu/TG/OZ/prodcfcs.html

(2010) Chlorofluorocarbons. Retrieved August 25, 2010. http://www.purdue.edu/envirosoft/housewaste/house/chlorofl.htm

(2010) How do Chlorofluorocarbons Affect Ozone Levels? Retrieved August 25, 2010. http://ozone.gi.alaska.edu/levels.htm

(2010) Loss of Stratospheric Ozone and Health Effects of Increased Ultraviolet Radiation. Retrieved August 25, 2010. http://www.ciesin.columbia.edu/docs/001-561/001-561.html

(2010) The Ozone Problem, CFC’s and Alternatives. Retrieved August 25, 2010. http://earthguide.ucsd.edu/virtualmuseum/climatechange2/10_2.shtml

(2010) Image by EA


4 comments

  • Comment Link Jerry Schmidt Saturday, 19 February 2011 09:11 posted by Jerry Schmidt

    We tend to think about carbon dioxide emissions when it comes to environmental air pollution. This article is a good reminder that there are other actions that we do, other than driving our cars, that can cause harm to our atmosphere. Good food for thought!

  • Comment Link Rosanne Barnes Tuesday, 07 June 2011 10:51 posted by Rosanne Barnes

    Thinking about how we've replaced one bad pesticide with another, one bad hormone used in meat with another, I have my concerns about what's to replace CFCs. It's like the void doesn't get erased, only filled by another product. Another product that takes time for the EPA to discover is just as hazardous as its predecessor. I'm not usually a pessimist. It's just hard to be informed and stay optimistic about what our organizations are/ are not doing to keep us safe here in the U.S. Maybe it's time to move to Europe.

  • Comment Link Ricco carman Tuesday, 05 July 2011 06:19 posted by Ricco carman

    This is ricco I have so many ideas to stop the cfc chemicals from destroying the ozone layer how can I oblige u in your conquest ,

  • Comment Link Process Engineers Wednesday, 07 December 2011 02:28 posted by Process Engineers

    Thank you for sharing this information.
    It really helps to clear up some confusion

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